Antimony porphyrins as red-light powered photocatalysts for solar fuel production from halide solutions in the presence of air.

نویسندگان

  • M Ertl
  • E Wöß
  • G Knör
چکیده

Halide ions (X(-)) as cheap and abundant electron donors are oxidized with simulated sunlight in a photocatalytic reaction based on robust antimony porphyrins acting as red-light harvesting multielectron transfer sensitizers. Besides halogen formation (X2/X3(-)) this solar energy storing process under certain conditions also accumulates hydrogen peroxide (H2O2) as a second energy-rich compound.

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عنوان ژورنال:
  • Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology

دوره 14 10  شماره 

صفحات  -

تاریخ انتشار 2015